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Consider the gaseous reaction of xenon and fluorine to form xenon hexafluoride.?
Consider the gaseous reaction of xenon and fluorine to form xenon hexafluoride.
(a) Calculate ΔS° at 298 K (ΔH° = -402 kJ/mol and ΔG° = -280. kJ/mol).
(b) Assuming ΔS° and ΔH° change little with temperature, calculate ΔG° at 517 K.
delta = "d" in the following. The free energy equation is:
dGo = dHo - T dSo
(a)
dSo = (dHo - dGo) / T = [-402 - (-280)] kJ/mol / 298 K
= -0.409 kJ / K mol or - 409 J/K mol
(b)
dGo = dHo - T dSo = - 402 kJ/mol - 517 K (-0.409 kJ/mol K)
= - 191 kJ/mol
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